High pressure geochemistry:Preface     

Jianguo Du  Baohua Zhang  Bo Zou  Bin Chen  Geeth Manthilake 《地学前缘(英文版)》2021,12(2)

The origin and history of the Earth are manifested as the evolutionary processes of chemistry and physics of its interiors,which can be recognized by deciphering the geochemical signals recorded in minerals and rocks.Deep interiors of the Earth and other rocky planets are under both extreme pressure and temperature,i.e.,approximately 360 gigapascals(GPa)and as high as 7000 K at the center of the Earth.  相似文献   

High-pressure phase transformation of carbonate malachite Cu2(CO3)(OH)2 driven by [CuO6] regularization and [CO3] rotation     

Jing Gao  Xueyin Yuan  Bin Chen  Zhenxian Liu  Wen Su 《地学前缘(英文版)》2021,12(2)

High-pressure synchrotron X-ray diffraction and infrared absorption spectroscopy have been employed to study the crystal chemistry and phase transitions in an[OH]-bearing carbonate,malachite Cu2(CO₃)(OH)₂,to determine the effect of[OH]on the stability of carbonate.We found that the crystal structure of malachite is stabilized by a high degree of[CuO₆]-octahedron distortion,as is manifested by large variations in Cu–O bond lengths resulting from oxygen atoms that connect to hydrogen at crystallographically different sites.External pressure offsets the effect of hydrogen bond,promotes[CuO₆]compression and regularization and accordingly[CO₃]rotation.Rotation of[CO₃]-triangles,in turn,assists in a conversion in the crystal orientation of the[CuO₆]structural unit.During compression to above~6 GPa,malachite begins to turn into the rosasite lattice,accompanied with a jump in density of 3.3%.Rosasite is characterized with a hardened lattice and preserves to the maximum pressure(18.2 GPa)of the present study.Phase transformation mechanism of malachite to rosasite is different from that of carbonates,with the latter being driven by an almost uniform compression of[MO₆]-octahedron(M=Ca,Cd,Mn,Fe,Zn,Mg,etc.)and rotation/translation of[CO₃]-triangle under pressure.  相似文献   

Response of ocean dynamics to multiple equilibria of the Kuroshio path South of Japan     

《Dynamics of Atmospheres and Oceans》2019

Variability of the Kuroshio path to the south of Japan plays a central role in the local climate change and exerts tremendous influences on the local atmosphere and ocean. In this study, the response of ocean dynamics, in terms of the eddy kinetic energy (EKE), potential vorticity (PV), relative vorticity, and eddy-mean flow interaction, to the Kuroshio path change is discussed. Kuroshio path south of Japan includes the near-shore non-large meander (nNLM), the off-shore non-large meander (oNLM), and the typical large meander (tLM). Analyses reveal that the distribution of EKE, PV, relative vorticity, and energy exchange between the eddy field and the mean flow respectively varies with the Kuroshio path: (1) The tLM has the maximum EKE along the path; (2) The positive and negative PV are located at the onshore and offshore side of Kuroshio axis, respevetively; (3) The distributions of anomalous relative voritcity of nNLM, oNLM, and tLM are consistent with sea surface height anomalies (SSHAs); (4) The tLM has the largest energy exchange between the eddy field and the mean flow in terms of the rate of barotropic energy conversion. On the other hand, the stability analysis of ocean currents suggests that the three Kuroshio paths south of Japan have their own intrinsic properties of the instability.  相似文献   

Relationship between summer rainfall anomalies and sub-seasonal oscillation intensity in the ChangJiang Valley in China     

《Dynamics of Atmospheres and Oceans》2015

Sub-seasonal variability of summer (May–October) rainfall over the ChangJiang Valley exhibits two dominant timescales, one with a quasi-biweekly (QBW) period (10–20 days) and the other with an intraseasonal oscillation (ISO) period (20–60 days). A significant positive correlation (at a 99% confidence level) was found between the summer precipitation anomaly and the intensity of the QBW and ISO modes in the region. By examining the composite structure and evolution characteristics, we note that the QBW mode is characterized by a northwest–southeast oriented wave train pattern, moving southeastward. The perturbations associated with the ISO mode propagate northwestward in strong ISO years but southeastward in weak ISO years. A marked feature is the phase leading of low-level moisture to convection in both the QBW and ISO mode. When the summer rainfall is strong in the ChangJiang Valley, large-scale atmospheric conditions in the strong QBW/ISO activity region are characterized by deeper moist layer, convectively more unstable stratification and greater ascending motion. Such mean conditions favor the growth of the QBW and ISO perturbations. Thus, a significant positive correlation between the summer precipitation and the strength of sub-seasonal variability arises from the large-scale control of the summer mean flow to perturbations.  相似文献   

On Factors Controlling Air–Water Gas Exchange in a Large Tidal River     

David T. Ho  Peter Schlosser  Philip M. Orton 《Estuaries and Coasts》2011,34(6):1103-1116

Air–water gas exchange is an important process in aquatic systems, including tidal rivers and estuaries. While there are now reliable and routine methods for determining gas exchange over a range of temporal and spatial scales in the ocean and these measurements have resulted in widely used wind speed parameterizations to calculate air–sea gas exchange, the same has not been true for coastal inland waterways. Some studies have suggested that this difference is methodological, while others point to the existence of additional drivers for gas exchange besides wind in rivers and estuaries. Here, we present gas transfer velocities measured in the tidal Hudson River with a method widely used in oceanic studies, the ³He/SF₆ dual tracer technique. Airside and waterside forcings were determined with an anemometer and an acoustic Doppler current profiler, respectively. The results confirm that wind is the dominant driver of gas exchange in the tidal Hudson River, with negligible contribution from bottom-generated turbulence. Furthermore, a parameterization between wind speed and gas exchange developed for the ocean is able to predict gas exchange in this environment with high accuracy. It is hoped that by transferring methodology used in oceanic studies to rivers and estuaries, robust data can be obtained that will eventually allow development of widely applicable relationships between easily measured environmental variables and gas exchange in tidal inland waters.  相似文献   

Temporal stability of Symbiodinium phylotype in scleractinian coral Galaxea fascicularis from a tropical fringing reef in the South China Sea     

�ܹ�ΰ  ����  ��־��  ����ţ 《中国海洋湖沼学报》2011,29(6):1186-1191

Symbiodinium sp. occurs in a symbiotic association with various marine invertebrates, including the scleractinian corals. Understanding the flexibility and specificity in coral-algal symbiosis can have important implications for predicting the future of coral reefs in the era of global climate change. In the present study, we conducted Symbiodinium phylotype analysis, based on polymerase chain reaction and restriction fragment length polymorphism (PCR-RFLP), in the scleractinian coral, Galaxea fascicularis, from a tropical fringing reef in Hainan Island, over a 1-yr period. Our results showed that Galaxea fascicularis could associate with Symbiodinium clade C and D either individually or simultaneously. However, during the sampling period, the Symbiodinium phylotype did not change significantly in the scleractinian coral Galaxea fascicularis, although the seawater temperature decreased sharply in the winter season. This study further suggests that the shift in Symbiodinium communities in response to seasonally fluctuating environments might not be a universal feature of coral-algal associations.  相似文献   

Sorption and desorption of dissolved organic phosphorus onto iron (oxyhydr)oxides in seawater   总被引：2，自引：0，他引：2  

K.C. Ruttenberg  D.J. Sulak 《Geochimica et cosmochimica acta》2011,75(15):4095-4112

Sorption of phosphorus (P) onto particulate surfaces significantly influences dissolved P concentrations in aquatic environments. We present results of a study contrasting the sorption behavior of several dissolved organic phosphorus (DOP) compounds and phosphate onto three commonly occurring iron (oxyhydr)oxides (Fe_ox): ferrihydrite, goethite, and hematite. The DOP compounds were chosen to represent a range of molecular weights and structures, and include: adenosine triphosphate (ATP), adenosine monophosphate (AMP), glucose-6-phosphate (G6P), and aminoethylphosphonic acid (AEP).All P compounds displayed decreasing sorption as a function of crystallinity of the Fe_ox substrate, with ferrihydrite adsorbing the most, hematite the least. In general, maximum sorption density decreased with increasing molecular weight of P compound; sorption of G6P onto goethite and hematite excepted. P compound size and structure, and the nature of the Fe_ox substrate all appear to play a role dictating relative sorption capacity. Failure of a simple, 1-step sorption-desorption model to describe the data suggests that P sorption cannot be explained by a simple balance between sorption and desorption. Instead, the data are consistent with a 2-step sorption model consisting of an initial rapid surface sorption, followed by a slow, solid-state diffusion of P from surface sites into particle interiors. Desorption experiments provide additional support for the 2-step sorption model.Without exception, DOP compounds showed less efficient sorption than did orthophosphate. This suggests that in aquatic systems enriched in reactive Fe_ox, whether as suspended particulates in the water column or in benthic sediments, DOP bioavailability may exceed that of orthophosphate. Since biological uptake of P from DOP requires enzymatic cleavage of orthophosphate, a system enriched in DOP relative to orthophosphate may impact ecosystem community structure.  相似文献   

Magma at depth: a retrospective analysis of the 1975 unrest at Mount Baker,Washington, USA     

Juliet G. Crider  David Frank  Stephen D. Malone  Michael P. Poland  Cynthia Werner  Jacqueline Caplan-Auerbach 《Bulletin of Volcanology》2011,73(2):175-189

Mount Baker volcano displayed a short interval of seismically-quiescent thermal unrest in 1975, with high emissions of magmatic gas that slowly waned during the following three decades. The area of snow-free ground in the active crater has not returned to pre-unrest levels, and fumarole gas geochemistry shows a decreasing magmatic signature over that same interval. A relative microgravity survey revealed a substantial gravity increase in the ~30 years since the unrest, while deformation measurements suggest slight deflation of the edifice between 1981–83 and 2006–07. The volcano remains seismically quiet with regard to impulsive volcano-tectonic events, but experiences shallow (<3 km) low-frequency events likely related to glacier activity, as well as deep (>10 km) long-period earthquakes. Reviewing the observations from the 1975 unrest in combination with geophysical and geochemical data collected in the decades that followed, we infer that elevated gas and thermal emissions at Mount Baker in 1975 resulted from magmatic activity beneath the volcano: either the emplacement of magma at mid-crustal levels, or opening of a conduit to a deep existing source of magmatic volatiles. Decadal-timescale, multi-parameter observations were essential to this assessment of magmatic activity.  相似文献   

Brief history of ground-based very high energy gamma-ray astrophysics with atmospheric air Cherenkov telescopes     

《Astroparticle Physics》2014

The discovery of the Crab Nebula as the first source of TeV gamma rays in 1989, using the technique of ground-based imaging air Cherenkov telescope, has marked the birthday of observational gamma astronomy in very high energy range. The team led by Trevor Weekes, after twenty years of trial and error, success and misfortune, step-by-step improvements in both the technique and understanding of gamma shower discrimination methods, used the 10 m diameter telescope on Mount Hopkins in Arizona, and succeeded measuring a 9σ signal from the direction of Crab Nebula. As of today over 160 sources of gamma rays of very different types, of both galactic and extra-galactic origin, have been discovered due to this technique. This is a really fast evolving branch in science, rapidly improving our understanding of the most violent and energetic sources and processes in the sky.The study of these sources provides clues to many basic questions in astrophysics, astro-particle physics, physics of cosmic rays and cosmology. Today’s telescopes, despite the young age of the technique, offer a solid performance. The technique is still maturing, leading to the next generation large instrument. This article is devoted to outlining the milestones in a long history that step-by-step have made this technique emerge and have brought about today’s successful source hunting.  相似文献   

Spatial Patterns of Sea Level Variability Associated with Natural Internal Climate Modes   总被引：1，自引：0，他引：1  

Weiqing Han  Gerald A. Meehl  Detlef Stammer  Aixue Hu  Benjamin Hamlington  Jessica Kenigson  Hindumathi Palanisamy  Philip Thompson 《Surveys in Geophysics》2017,38(1):217-250

Sea level rise (SLR) can exert significant stress on highly populated coastal societies and low-lying island countries around the world. Because of this, there is huge societal demand for improved decadal predictions and future projections of SLR, particularly on a local scale along coastlines. Regionally, sea level variations can deviate considerably from the global mean due to various geophysical processes. These include changes of ocean circulations, which partially can be attributed to natural, internal modes of variability in the complex Earth’s climate system. Anthropogenic influence may also contribute to regional sea level variations. Separating the effects of natural climate modes and anthropogenic forcing, however, remains a challenge and requires identification of the imprint of specific climate modes in observed sea level change patterns. In this paper, we review our current state of knowledge about spatial patterns of sea level variability associated with natural climate modes on interannual-to-multidecadal timescales, with particular focus on decadal-to-multidecadal variability. Relevant climate modes and our current state of understanding their associated sea level patterns and driving mechanisms are elaborated separately for the Pacific, the Indian, the Atlantic, and the Arctic and Southern Oceans. We also discuss the issues, challenges and future outlooks for understanding the regional sea level patterns associated with climate modes. Effects of these internal modes have to be taken into account in order to achieve more reliable near-term predictions and future projections of regional SLR.  相似文献